《Table 1 Selected bond lengths () and angles (°) for 2》

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《半竹节虫型双金属配合物制备铁铂纳米颗粒及其图案化阵列的磁存储应用（英文）》

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The molecular structure of complex 2 in the solid state was established by X-ray crystallography and is shown in Fig.1a.The metric parameters are given in the supporting information and the selected bond distances and angles are listed in Table 1.The crystals were grown by slow vapour diffusion of Et2O into a chloroform solution of 2.The structure revealed that the Pt ion binds tightly to the three adjacent coplanar sites and an irregular squareplanar motif was formed.A linear chain-like packing between molecules was observed with the Pt···Pt bonds that stacked on top of each other in a head-to-tail fashion，while the ferrocenyl groups in the two adjacent molecules were arranged in the opposite directions.The torsion angle of Pt···Pt···Pt is 115.97°，and the distances of the stacking plane are measured to be alternate between 3.408and 3.450?.In addition，their absorption spectra were recorded in solution phase（Fig.S2）.The broad peak from the ferrocenyl group was obviously shifted from 460 nm to 520 nm after coordination with the metal center，and the shoulder peak at 375 nm appeared owing to the intermolecular metal-to-ligand charge transfer（MLCT）and intraligand transitions[38，39].