《Table 2 Acidity of H-ZSM-5 ze olite s with diffe re nt SiO2/Al2O3ratios》

《Table 2 Acidity of H-ZSM-5 ze olite s with diffe re nt SiO2/Al2O3ratios》   提示:宽带有限、当前游客访问压缩模式
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《H-ZSM-5分子筛硅铝比对其催化的甲醇转化丙烯选择性的影响(英文)》


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a:the amounts of weak,medium,and strong acid sites were calculated from the NH3-TPD profiles by integrating the ammonia desorption lines in the range of 373-500,500-600,and 600-923 K,respectively;b:the ratio of Brnsted to Lewis(B/L)acidity is obta

Figure 1 show s the XRD patterns of H-ZSM-5zeolites;all the synthesized samples display the typical diffraction peaks of intrinsic M FI structure.Taking HZ-5(4000)zeolite as a reference,they all havearelativecrystallinityof90%-100%,demonstrating their highly crystalline M FI structure.The textural properties determined from the nitrogen adsorption-desorption isotherms are summarized in Table 1;all the synthesized H-ZSM-5 samples have a similar BET surface area(415-430 m2/g)and micro surface area(306-341 m2/g),as w ell as almost the same pore volume(0.20 cm3/g)and micropore volume(0.15 cm3/g).In addition,as estimated by Scherrer’s method from the diffraction peak of(011)plane at 7.9°,all the as-synthesized samples have a similar crystal size of 66-73 nm(Table 1).