《Table 2 Activation energies of Pd-Rh bimetallic catalysts for CO oxidation with a varied compositio

《Table 2 Activation energies of Pd-Rh bimetallic catalysts for CO oxidation with a varied compositio   提示:宽带有限、当前游客访问压缩模式
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《PdRh双金属纳米立方体表面化学原位研究与CO氧化反应催化性能的关联(英文)》


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To measure activation barriers of CO oxidation on these catalysts,CO oxidation was performed in the kinetically controlled region(the conversion of CO≤15%).Fig.8presents the Arrhenius plots of PdxRh1-xbimetallic NCs,Pd0.8Rh0.2,Pd0.6Rh0.4,and Pd0.2Rh0.8upon the two different pretreatment methods(H2-reaction-O2versus H2-O2).Because Pd0.2Rh0.8-H2-reaction-CO and Pd0.2Rh0.8-H2-O2exhibited the same surface composition and the same valence state(Figs 6 and 7),only Pd0.2Rh0.8-H2-O2was evaluated by the kinetic study.Table 1 lists the activation energies calculated from the Arrhenius plots for the catalysts pretreated by different methods.