《Table 2 Activation energies of Pd-Rh bimetallic catalysts for CO oxidation with a varied compositio
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《PdRh双金属纳米立方体表面化学原位研究与CO氧化反应催化性能的关联(英文)》
To measure activation barriers of CO oxidation on these catalysts,CO oxidation was performed in the kinetically controlled region(the conversion of CO≤15%).Fig.8presents the Arrhenius plots of PdxRh1-xbimetallic NCs,Pd0.8Rh0.2,Pd0.6Rh0.4,and Pd0.2Rh0.8upon the two different pretreatment methods(H2-reaction-O2versus H2-O2).Because Pd0.2Rh0.8-H2-reaction-CO and Pd0.2Rh0.8-H2-O2exhibited the same surface composition and the same valence state(Figs 6 and 7),only Pd0.2Rh0.8-H2-O2was evaluated by the kinetic study.Table 1 lists the activation energies calculated from the Arrhenius plots for the catalysts pretreated by different methods.
图表编号 | XD0039959100 严禁用于非法目的 |
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绘制时间 | 2019.01.01 |
作者 | 朱威、单军军、Luan Nguyen、张适然、陶丰、张亚文 |
绘制单位 | Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, PKU-HKU Joint Laboratory in Rare Earth Materials and Bioinorganic Chemistry, College of Chemistry and Molecular Engineering, Pekin |
更多格式 | 高清、无水印(增值服务) |
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