《Table 3.Activation energies of permeation for CO2and N2through Pebax1074 mem-brane and its blend me

《Table 3.Activation energies of permeation for CO2and N2through Pebax1074 mem-brane and its blend me   提示:宽带有限、当前游客访问压缩模式
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《Effect of poly(ethylene glycol) molecular weight on CO_2/N_2 separation performance of poly(amide-12-b-ethylene oxide)/poly(ethylene glycol) blend membranes》


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where,P0is the pre-exponential factor,EPthe apparent activation energy for permeation,R the gas constant,and T the temperature.According to DSC data in Table 1,there was also no thermal transition within the temperature range between 35°C and 75°C for Pebax1074,Pebax1074/PEG200 and Pebax1074/PEG400 blend membranes,so their gas permeation characteristics were similar with those of Pebax1074/PEG600 blend membrane,which can also be described by Arrhenius equation.The activation energies of permeation for CO2and N2are listed in Table 2.Because the low molecular weight PEG was beneficial to the gas diffusivity and solubility[23],its addition into Pebax1074 membrane made the activation energies for CO2and N2smaller than those of Pebax1074.And they both decreased with the increase of PEG molecular weight,which was consistent with the Tgof Pebax1074/PEG blend membranes with low molecular weight PEG as shown in Table 1.