《Table 1 BET analysis of pure Zn O, BiOI and BiOI/Zn O hybrid nanoflowers》

《Table 1 BET analysis of pure Zn O, BiOI and BiOI/Zn O hybrid nanoflowers》   提示:宽带有限、当前游客访问压缩模式
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《新型ZnO/BiOI杂化纳米花的合成及可见光驱动抗菌活性(英文)》


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N2adsorption-desorption isotherm measurement was performed to investigate the surface and porous structures of Zn O,BiOI and Zn O/BiOI nanoflowers.As shown in Fig.5,BiOI and Zn O/BiOI hybrid nanoflower display type-Ⅳisotherms with a distinct hysteresis loop in the range of 0.5—1.0(P/P0)indicating the presence of mesoporous structure[27].The conclusion is fully supported by the pore size distribution curves(inset)obtained from the N2isotherms.According to the result,the specic BET surface areas of Zn O,BiOI and Zn O/BiOI nanoflowers are 3.59m2·g-1,47.65 m2·g-1,55.61 m2·g-1,respectively.The deposition of BiOI not only had an obvious effect on the morphology of Zn O/BiOI composites,but also could greatly increase the absorbed area.Besides,the total pore volume also increases greatly from 0.017 cm3·g-1of Zn O and 0.166 cm3·g-1of BiOI to 0.231 cm3·g-1of Zn O/BiOI hybrid nanoflowers(Table1).The existence of large number of pore structure greatly enhances the specific surface area of Zn O/BiOI nanocomposites,and promotes the absorption of photons and the activation of Zn O and BiOI produce more electron-hole pairs,which improves the photocatalytic performance of the material[28].What’s more,the large pore of ZnO/BiOI allows an easy diffusion of pathogens in and around the nanocomposites,thus it can enhance the adsorption of pathogens,and it intermediates on the surface of the photocatalysts as well.