《Tab.2 Comparison of selected bond lengths () and angles (°) for complexes 2, 3, 4》

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《新型硫/氧钼配合物(Et_4N)_2[MoO(S_4)(bdtX_2)]和(Et_4N)_2[Mo_2O_2(m_2-S)_2(bdtX_2)]的合成及晶体结构（英文）》

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Crystallographic data and experimental details for（Et4N）2[Mo O（S4）（bdt Cl2） ]（2），（Et4N） 2[Mo2O2（m2-S）2（bdt）]（3）and（Et4N）2[Mo2O2（m2-S）2（bdt Cl2）]（4）are summarized in Tab.1.The selected bond lengths and bond angles are listed in Tab.2.Intensity data were collected on a Bruker SMART APEX 2000 CCD diffractometer using graphite-monochromated Mo K radiation（l=0.710 73?）at 296（2）K.The collected frames were processed with the software SAINT.The data were corrected for absorption using the program SADABS.The structures were solved by Direct Methods and refined by full-matrix least-squares on F2using the SHELXTL software package.All non-hydrogen atoms were refined anisotropically except the[Et4N]+cations in complex 2 due to the obviously disordered.The positions of all hydrogen atoms were generated geometrically（Csp3H=0.97 and Csp2H=0.93?），assigned isotropic displacement parameters，and allowed to ride on their respective parent carbon or nitrogen atoms before the final cycle of least-squares refinement.The largest peak in the final difference maps had height of 1.131 e·?-3for 2 are in the vicinity of the molybdenum atom.