《Table 2 Elemental surface composition of CNC-Br and CNC-PDMAEMA, as determined by XPS》

《Table 2 Elemental surface composition of CNC-Br and CNC-PDMAEMA, as determined by XPS》   提示:宽带有限、当前游客访问压缩模式
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《Functionally Modified Cellulose Nanocrystals as an Adsorbent for Anionic Dyes》


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FT-IR and XPS analyses were carried out to examine the chemical structure and surface elements of CNC-Br and CNC-PDMAEMA.BIBB was anchored on the surface of CNC by esterification to prepare the ATRP initiator.As shown in Fig.1(b),unlike CNC,CNC-Br showed a strong FT-IR peak at 1740 cm-1.This peak corresponds to the stretching vibration of C=O from the ester group[19].A strong peak at 1280 cm-1 corresponding to C—O was observed in the FT-IR spectrum of CNC-Br(Fig.1 (b)) [20].The XPS spectrum of CNC-Br(Fig.2)showed a Br3d peak at 68 eV.It can be observed from Table 2 that the Br content in CNC-Br was 3.01%.These results suggest that BIBB was successfully grafted onto the CNC surface(reaction is shown in Scheme 1).