《Table 1 Compositions for preparing the oxide electrodes》

《Table 1 Compositions for preparing the oxide electrodes》   提示:宽带有限、当前游客访问压缩模式
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《Oxygen Evolution Efficiency and Chlorine Evolution Efficiency for Electrocatalytic Properties of MnO_2-based Electrodes in Seawater》


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Thermal decomposition was adopted to prepare an IrO2 coating as an intermediate layer on the titanium substrate[10,15].The IrO2 coating was prepared by the following procedure:first,a precursor of a 0.2 M chloroiridic acid butanol solution was prepared;it was then painted with a brush on the titanium substrates using three coats,which after each coat were dried at100℃for 10 min and then sintered at 450℃for 10min;then,this specimen was finally sintered for 1 h at450℃;the electrodes were then anodically polarized at 1 000 A·m-2 for 10 min in 0.1 M H2SO4 at room temperature to remove any contaminants;finally,Mn,Mn+Mo,Mn+Mo+V,and Mn+Fe+V oxide electrode coatings were prepared on the electrodes by anodic deposition at 90℃with a constant current density of 600 A·m-2 for 60 min.The composition of the resultant oxide electrodes are listed in Table 1.The pH value of the electrolyte was buffered to 0.5 by using concentrated sulfuric acid.Pure(>99.98%)titanium was employed as a counter electrode.