《Table 2–Freundlich parameters of estrogens (E2 and E1) sorption in the presence and absence of bioc

《Table 2–Freundlich parameters of estrogens (E2 and E1) sorption in the presence and absence of bioc   提示:宽带有限、当前游客访问压缩模式
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《Effect of biochar on fate and transport of manure-borne estrogens in sandy soil》


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The effective distribution coefficient(Kdeff)values of SB treatments were significantly higher(H0:p<0.05)than soil treatment(Table 2).Although both biochars effectively improved retention of estrogens in soil,the sorption coefficients of both estrogens were significantly(p<0.05)higher in SBS450than SBH750.The sorption behavior of biochars is a function of the physiochemical and structural characteristics(Kim et al.,2016).The elemental composition of BS450with lower H/C molar ratio(0.34)than that of BH750(0.55)confirms the higher aromaticity of BS450with more organic carbon(Jung et al.,2013).The enhanced sorption sites of biochar with lower H/C molar ratios are correlated to their higher carbon content(Salvia et al.,2014;Zheng et al.,2010).Similarly,Hao et al.(2013)correlated the increased adsorption of atrazine on corncob biochars with decreased H/C and(O+N)/C ratios.The higher aromaticity of BS450enhanced the interaction of both estrogens with aromatic adsorptive sites of biochar viaп-пelectron donor-acceptor interactions resulting in higher Kf values(Kupryianchyk et al.,2016).