《Table 3Scope of alcohols a.》

《Table 3Scope of alcohols a.》   提示:宽带有限、当前游客访问压缩模式
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《可见光催化喹喔啉-2(1H)-酮与醇C(sp~2)-H/O-H交叉脱氢偶联反应(英文)》


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In conclusion,we have reported for the first time,a visi‐ble‐light photocatalytic C(sp2)‐H/O‐H cross‐dehydrogenation coupling of quinoxalin‐2(1H)‐ones and alcohols employing ambient air as an oxidant at room temperature,providing an eco‐friendly and efficient route to access a wide range of3‐alkoxylquinoxalin‐2(1H)‐ones.The easily available raw ma‐terials,low catalyst loading(2 mol%),excellent functional group tolerance,sustainable dioxygen oxidant,metal‐free reac‐tion conditions,good to excellent yields,excellent at‐om‐economy,and scalability of the present photocatalytic reac‐tion make it very attractive in the pharmaceutical industry and for organic synthesis.