《Table 1The BSA and TPV values determined from the N2 adsorption‐desorption isotherms, and the N and

《Table 1The BSA and TPV values determined from the N2 adsorption‐desorption isotherms, and the N and   提示:宽带有限、当前游客访问压缩模式
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《碳模板诱导生长Fe-N_x活性位点(英文)》


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N2 adsorption/desorption isotherms and the Bar‐rett‐Joyner‐Halenda(BJH)pore‐size distribution(Fig.S1)are key to elucidating the structures of the formed nanocarbons.The pore sizes of the samples containing nanotubes(i.e.,Fe N‐CNT/CS and Fe N‐CNT)are in the range of~0–100 nm;in comparison,the pore sizes of N‐CS are in the range of~50–1000 nm.Therefore,the Brunauer‐Emmett‐Teller(BET)surface areas(BSAs)and total pore volumes(TPVs)of Fe N‐CNT/CS and Fe N‐CNT can be attributed to the mesoscale pores.Table 1 shows that the BSA and TPV values of Fe N‐CNT/CS are 177 m2/g and 0.41 cm3/g,respectively,which facilitate the dispersion of the Fe‐Nx species.Both the single materials provided lower BSA and TPV values:68 m2/g and0.21 cm3/g,respectively,for Fe N‐CNT and 160 m2/g and 0.36cm3/g,respectively,for N‐CS.From these results,it is reasona‐ble to propose that there is an effective synergy between the nanotubes and CS in Fe N‐CNT/CS that does not occur in the absence of either component.This supports that the CS tem‐plate promotes both the formation of Fe‐Nx active sites and ORR performance.