《Table 3 Oligomerizations activated by the reaction products of 2-NaphOH/cyclohexanol, AlMe3 and wat

《Table 3 Oligomerizations activated by the reaction products of 2-NaphOH/cyclohexanol, AlMe3 and wat   提示：宽带有限、当前游客访问压缩模式
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《Preparation of Aryloxy-aluminoxanes and Their Use as Activators in the Bis(imino)pyridyl Iron-catalyzed Oligomerization of Ethylene》


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a General conditions:pre-cat.:L-Fe（acac）3，[Fe]=2μmol；[Al]/[Fe]=2000；solvent:toluene，50 mL；T=50°C；P=0.1 MPa；t=30 min；b The mass fraction of insoluble polymers in the total products；c Total activity:kg/ （mol Fe·h）

Besides the utilization of PhOHs as the[―OH]source in thefirst step of reaction with AlMe3，two other types of[―OH]2-naphthol and cyclohexanol，were also explored for th preparation of aluminoxane activators.The preparatio conditions were identical to the aforementioned ones with th[H2O]/[Al]ratio used in the hydrolysis procedure to be 0.7The results are summarized in Table 3.

图表编号XD0020171900    严禁用于非法目的
绘制时间2018.11.01
作者Wei Zhang、Bin-Bo Jiang、Jian Ye、Zu-Wei Liao、Zheng-Liang Huang、Jing-Dai Wang、Yong-Rong Yang
绘制单位Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University、Zhejiang Provincial Key Laboratory of Advanced Ch
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