《Table 1 Crystal data and structure parameters for complex 1》

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《一种2-甲基-3-羟基喹啉-4-甲酸单核铜(Ⅱ)配合物的合成、晶体结构、理论计算与性质（英文）》

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The X-ray diffraction data was collected on a SuperNova CCD X-ray diffractometer with a carefully selected single crystal（the dimension of 0.37 mm×0.19mm×0.13 mm）.The X-ray source was graphite monochromatic Mo Kαradiation with theλbeing o0.071 073 nm.The reduction and empirical absorption correction of the diffraction data were carried out with the CrystalClear software.The crystal structure was solved by means of the direct method and the Siemens SHELXTL V5 software and refined with a full-matrix least-squares refinement on F2[25].All non-hydrogen atoms were located on the difference Fourier maps and applied anisotropic refinement.The hydrogen atoms，except for water and methanol，were theoretically attached to their parent atoms and included in the structural factor calculations with assigned isotropic thermal parameters.The summary of the crystallographic data for the complex is provided in Table 1.The selected bond distances and angles are listed in Table 2.