《Table 1 Conditions for the ADMET polymerization of monomers a and analytical data of the resulting

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《Perylene Bisimide In-chain Polyethylene with Unique Self-assembly Nanostructure through Acyclic Diene Metathesis(ADMET) Polymerization》

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a Reaction conditions:[Monomer]0:[Catalyst]0=50:1，[Monomer]0=0.5 mol/L，temperature=60°C，polymerizations were conducted in chloroform（P1a'–P1d'）or toluene（P1a–P1d）with Ru-II as the catalyst；b Obtained gravimetrically after purification from the dr

As an initial attempt，ADMET reaction of M1 was carried out in CHCl3，the orange-red color gradually changed to red，and finally dark-red solid P1 was obtained in a high yield by precipitating the reaction mixture from excess ethyl ether.The polymerization conditions and results are listed in Table 1.