《Table 3 Pseudo-first-and second-order parameters for the adsorption》

《Table 3 Pseudo-first-and second-order parameters for the adsorption》   提示:宽带有限、当前游客访问压缩模式
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《Functionally Modified Cellulose Nanocrystals as an Adsorbent for Anionic Dyes》


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The adsorption kinetics of CNC-PDMAEMA based on the pseudo first-and second-order models are shown in Fig.7,and the estimated kinetic parameters are listed in Table 3.At the tested temperatures,the R2 for the second-order model was>0.99,while that for the firstorder model was found to be within the range 0.84~0.88.Moreover,the Qe,cal values(81.56 mg/g at 20℃,89.58mg/g at 30℃)for the pseudofirst-order model were much lower than the Qe,exp values(99.69 mg/g at 20℃,114.80mg/g at 30℃).On the other hand,the Qe,cal values(111.11mg/g at 20℃,125.00 mg/g at30℃)for the second-order model matched well with the Qe,exp values.This indicates that the adsorption kinetics of CNC-PDMAEMA were better described by the pseudosecond-order model.Thissuggests that the adsorption of the anionic dye onto the CNC-based adsorbent was mainly controlled by chemisorption[25-26].The pseudo-second-order kinetics of dye adsorption have also been reported for other biomass-based materials[25,27].