《Table 3 The properties of stabilized fibers and carbon fibers.》

《Table 3 The properties of stabilized fibers and carbon fibers.》   提示:宽带有限、当前游客访问压缩模式
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《沥青前驱体氧形态对其沥青与炭纤维性能的影响(英文)》


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Yield,stabilization and carbonization yield by tube furnace.ΔO,uptake of oxygen content.

The w eight gain started at about 160℃and reached the maxima of 106.5%at 335℃,105.9%at 329℃and 106.5%at 337℃for P200AT-PF,P250AT-PF and P300AT-PF,respectively.This meant a higher oxidation reactivity of P250AT-PF because it reached the maximum at a low est temperature,w hich w as ascribed to its higher methyl carbon content.The highest yields w ere 113.3%for P200AT-SF,112.0%for P300AT-SF and 110.5%for P250AT-SF.How ever,the oxygen contents of P200AT-SF,P250AT-SF and P300AT-SF presented in Table 3 w ere 19.16%,17.34%and 17.45%,respectively.It w as obvious that P250AT-PF show ed a less oxygen uptake of 15.83%than that of P200AT-PF(18.00%)and P300AT-CF(16.72%)during stabilization.This could be ascribed to the fact that P250AT had a higher oxygen content,w hich decreased the oxygen uptake and led to a low er stabilization yield.In addition,the released gases w ere mainly H2,CH4,H2O,CO and CO2during stabilization as revealed by TG-M S show n in Fig.4(b-f).H2w as released betw een 170 and 560℃,the main peak w as located at 350℃,w hich w as accompanied by a shoulder at about 490℃.The evolution of CH4took place betw een 430 and 650℃and reached a maximum at about 510℃.H2and CH4w ere released at slightly low er temperatures and less amounts for P200AT-PF than P250AT-PF and P300AT-PF because of its higher content of aliphatic chain[25,26].M ore H2O w as released from oxidative dehydrogenation reaction mainly at about 650℃for P200AT-PF than the other tw o PFs.M oreover,CO and CO2w ere escaped w ith a main peak at about 350 and 510℃,respectively.It is noticed that the CO and CO2w ere released at higher temperatures w ith slightly less amounts for P300AT-PF than P250AT-PF and P200AT-PF,because P300AT-PF w as more difficult to be oxidized ow ing to its higher aromaticity.