《Table 3.Products distribution of the n-octane hydroisomerization over the catalysts at the similar

《Table 3.Products distribution of the n-octane hydroisomerization over the catalysts at the similar   提示:宽带有限、当前游客访问压缩模式
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《Effect of preparation method on the bimetallic NiCu/SAPO-11 catalysts for the hydroisomerization of n-octane》


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A detailed product distribution for the catalysts at the similar conversion is shown in Table 3.For all the catalysts,the main n-octane isomers were 2-methyl heptane(2-MC7)and 3-methyl heptane(3-MC7).The ring opening of the octane protonated cyclopropane(PCP)intermediate at terminal position facilitated the formation of 2-MC7and 3-MC7[35].Among the di-methyl hexanes(DMC6)products,the 2,5-DMC6and 2,4-DMC6were major products,which was due to the further skeleton isomerization of2-MC7[35].The NiCu-CI,NiCu-CP,and CuNi-SI catalysts showed higher selectivity to n-octane isomers than the other catalysts.The NiCu-OMM catalyst showed the lowest selectivity to n-octane isomers.The Ni Cu-SI and Ni Cu-AM catalysts showed slightly higher selectivity to DMC6,but they also showed higher selectivity toβ-scission products.The cracking products containedβ-scission products and hydrogenolysis products.For the NiCu-OMM catalyst,it exhibited higher selectivity to cracking products than the other catalysts.The selectivity toβ-scission products for the Ni Cu-OMM catalyst was slightly higher than those for the other catalysts.However,the NiCu-OMM catalyst showed much higher selectivity to hydrogenolysis products than the other catalysts.Because the NiCu-OMM catalyst hardly formed the Ni-Cu alloy,the hydrogenolysis reaction was not restrained.For the cracking products over the Ni Cu-SI and Ni Cu-AM catalysts,the selectivity to hydrogenolysis products was low,indicating that the hydrogenolysis reaction was restrained.The selectivity to cracking products was due to the formation ofβ-scission products.Theβ-scission products were formed from the octane intermediates when the metal and acid sites were not balanced.Combined with the results shown in Figs.8 and 9,the NiCu-CI catalyst exhibited both high conversion of noctane and selectivity to n-octane isomers.Therefore,the Ni Cu-CI catalyst showed both excellent catalytic activity and isomerization selectivity in the hydroisomerization of n-octane.