《Table 1 Effect of ligands on hydroesterification reaction》

《Table 1 Effect of ligands on hydroesterification reaction》   提示:宽带有限、当前游客访问压缩模式
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《Preparation of Sodium Cobalt Tetracarbonyl and Optimization of Process Conditions for Hydroesterification of Ethylene Oxide》


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Phosphine ligands and N-ligands have received widespread attenti on in ligand selection for hydroformylation and hydro-methyl esterification of epoxide derivatives conducted over the carbonyl cobalt catalysts[19-20].Under the reaction conditions covering a temperature of 65°C,a time of 7 h,a pressure of6 MPa,and a methanol/EO molar ratio of 3:2,the effects of ligand-free condition,the phosphine ligand(triphenylphosphine oxide),the quaternary ammonium salt ligand(tetrabutylammonium bromide),and the N-containing ligand(imidazole,3-hydroxypyridine)on hydroesterification of ethylene oxide were studied,with the results shown in Table 1.