《POLYCYCLIC HYDROCARBONS VOLUME I》

PART ⅠGeneral1

CHAPTER 1．Nomenclature of Polycyclic Hydrocarbons3

CHAPTER 2．Carbon Atoms,p-Electrons and Hybridization12

CHAPTER 3．The C=C Double Bond and Conjugation in Butadiene14

CHAPTER 4．Theories about the Aromatic Bonds in Benzene19

CHAPTER 5．The Significance of Double Bonds and Kekulé Struc-tures for the Stability of Aromatic Systems24

CHAPTER 6．The Aromatic Sextet and its Significance in Relation to the Stability of Aromatic Systems32

CHAPTER 7．The Annellation Principle40

CHAPTER 8．Asymmetric Annellation Effects70

CHAPTER 9．The Relation between p-,α-and β-Bands,Phos-phorescence Bands and the Reactive p-State in Aromatic Hydrocarbons86

CHAPTER 10．The Ionization Potentials and the Electronic Levels of the Aromatic Sextet105

CHAPTER 11．The Tautomerism of Phenols108

CHAPTER 12．The Relation between Hydroquinols and Quinones110

CHAPTER 13．Magnetic Properties of Aromatic Hydrocarbons113

CHAPTER 14．The Electrical Conductivity of Aromatic Hydro-carbons118

CHAPTER 15．The C-C Bond Length in Polycyclic Hydrocarbons119

CHAPTER 16．Non-coplanar,Overcrowded Aromatic Hydrocarbons126

CHAPTER 17．The Possibility of Bond Fixation by Substitution130

CHAPTER 18．Carcinogenesis by Polycyclic Aromatic Hydrocar-bons and by Certain Other Carcinogens,by Regina Schoental133

CHAPTER 19．General Methods for the Preparation of Aromatic Hydrocarbons161

PART Ⅱkata-Annellated Hydrocarbons199

CHAPTER 20．Benzene:201

CHAPTER 21．Hydrocarbons Containing up to Two Linearly Annellated Benzene Rings:211

Ⅰ．Naphthalene211

Ⅱ．Phenanthrene223

Ⅲ．Triphenylene236

Ⅳ．Chrysene243

Ⅴ．3．4-Benzophenanthrene256

Ⅵ．1．2-Benzochrysene264

Ⅶ．Picene268

Ⅷ．5．6-Benzochrysene275

Ⅸ．3．4,5．6-Dibenzophenanthrene277

Ⅹ．Hexahelicene281

Ⅺ．1．2,7．8-Dibenzochrysene283

Ⅻ．11．12,13．14-Dibenzopicene285

ⅩⅢ．1．2,3．4,5．6,7．8,9．10,11．12-Hexabenzotriphenylene286

CHAPTER 22．Hydrocarbons Containing Three Linearly Annellated Benzene Rings:288

Ⅰ．Anthracene288

Ⅱ．Tetraphene307

Ⅲ．1．2,3．4-Dibenzanthracene322

Ⅳ．1．2,5．6-Dibenzanthracene329

Ⅴ．1．2,7．8-Dibenzanthracene337

Ⅵ．1．2,3．4,5．6-Tribenzanthracene341

Ⅶ．1．2,3．4,5．6,7．8-Tetrabenzanthracene343

Ⅷ．1．2-Benzotetraphene345

Ⅸ．3．4-Benzotetraphene347

Ⅹ．3．4,8．9-Dibenzotetraphene351

Ⅺ．Pentaphene353

Ⅻ．3．4-Benzopentaphene358

ⅩⅢ．3．4,9．10-Dibenzopentaphene361

ⅩⅣ．1．2,5．6-Dibenzotetraphene363

ⅩⅤ．6．7-Benzopentaphene365

ⅩⅥ．Dinaphtho-(2′．1′:1．2);(2 ″．1 ″:5．6)-anthracene367

ⅩⅦ．Naphtho-(2′．3′:6．7)-pentaphene368

ⅩⅧ．Naphtho-(2′．3′:3．4)-pentaphene371

ⅩⅨ．Anthraceno-(2′．1′:1．2)anthracene375

ⅩⅩ．Anthraceno-(2′．1′:8．9)-tetraphene378

ⅩⅪ．Tetrapheno-(9′．8′:8．9)-tetraphene379

ⅩⅫ．2．3-Benzopicene380

ⅩⅩⅢ．2．3,8．9-Dibenzopicene382

ⅩⅩⅣ．Anthraceno-(1′．2′:1．2)-tetraphene383

CHAPTER 23．Hydrocarbons with Four Linearly Annellated Benzene Rings:386

Ⅰ．Tetracene386

Ⅱ．1．2-Benzotetracene401

Ⅲ．1．2,3．4-Dibenzotetracene406

Ⅳ．1．2,7．8-Dibenzotetracene409

Ⅴ．1．2,9．10-Dibenzotetracene411

Ⅵ．1．2,3．4,7．8-Tribenzotetracene413

Ⅶ．1．2,3．4,7．8,9．10-Tetrabenzotetracene414

Ⅷ．Hexaphene416

Ⅸ．Heptaphene418

Ⅹ．7．8-Benzoheptaphene420

CHAPTER 24．Hydrocarbons with Five Linearly Annellated Rings:423

Ⅰ．Pentacene423

Ⅱ．1．2-Benzopentacene436

Ⅲ．1．2,3．4-Dibenzopentacene438

Ⅳ．1．2,8．9-Dibenzopentacene440

and 1．2,10．11-Dibenzopentacene440

Ⅴ．1．2,3．4,8．9,10．11-Tetrabenzopentacene443

CHAPTER 25．Hydrocarbons with Six Linearly Annellated Rings:447

Ⅰ．Hexacene447

Ⅱ．1．2-Benzohexacene452

CHAPTER 26．Hydrocarbons with Seven Linearly Annellated Rings:Heptacene455

CHAPTER 27．Hydrocarbons with Eight and More Linearly Annellated Rings:462

Ⅰ．Octacene462

Ⅱ．Nonacene463

ⅢUndecacene464

AUTHOR INDEX467