《ELECTROLYTE SOLUTIONS》

1．PROPERTIES OF IONIZING SOLVENTS1

2．BASIC CONCEPTS AND DEFINITIONS24

3．THE STATE OF THE SOLUTE IN ELECTROLYTE SOLUTIONS49

4．IONIC DISTRIBUTION FUNCTIONS AND THE POTENTIAL73

5．THE MEASUREMENT OF CONDUCTIVITIES AND TRANSPORT NUMBERS87

6．THE LIMITING MOBILITIES OF IONS118

7．THE VARIATION OF CONDUCTIVITIES AND TRANSPORT NUMBERS WITH CONCENTRATION133

8．THE MEASUREMENT OF CHEMICAL POTENTIALS174

9．THE THEORETICAL INTERPRETATION OF CHEMICAL POTENTIALS223

10．THE MEASUREMENT OF DIFFUSION COEFFICIENTS253

11．THE THEORY OF DIEFUSION OF ELECTROLYTES;CONDUCTANCE AND DIFFUSION IN RELATION TO VISCOSITY IN CONCENTRATED SOLUTIONS284

12．WEAK ELECTROLYTES336

13．THE＇STRONG＇ACUDS370

14．ION ASSOCLATION392

15．THE THERMODYNAMICS OF MIXED ELECTROLYTES432

APPENDICES457

INDEX553

LIST OF APPENDICES457

1．1 and 1．2Physical Properties of Water and other Solvents457

2．1 Relation between Activities and Mean Activity Coefficients459

2．2 The Function σ(x)460

2．3 The Function φ° for 2∶1 and 1∶2 Electrolytes460

3．1 Table of Ionic Radii461

5．1 Specific Conductivities of Potassium Chloride Solutious462

6．1 Limiting Equivalent Conductivities at 25° in Water463

6．2 Limiting Equivalent Conductivities of Ions in Water at Various Temperatures465

6．3 Equivalent Conductivity of Typical Electrolytes up to High Concentrations in Aqueous Solution at 25°466

7．1 Values of Parameters in Debye-Hückel-Onsager Equations for Aqueous 1∶1 Electrolytes468

8．1 Values of k=2·3026RT/F and of RT/F2469

8．2 Standard Potentials of Cells(Molality Scale)470

8．3 Water Activities,Molal Osmotic Coefficients,Molal Activity Coefficients,and Relative Molal Vapour Pressure Lowerings of Sodium and Potassium Chloride Solutions at 25°476

8．4 Water Activities,Molal Osmotic Coefficients,and Molal Activity Coefficients of Sulphuric Acid Solutions at 25°477

8．5 Water Activities,Molal Osmotic Coefficients and Molal Activity Coefficients of Calcium Chloride Solutions at 25°478

8．6 Water Activities,Molal Osmotic Coefficients and Molal Activity Coefficients of Sucrcee Solutions at 25°478

8．7 Molal Activity Coefficients at the Temperature of the Freezingpoint of the Solution479

8．8 Molal Osmotic and Activity Coefficients of Sodium Chloride and Potassium Bromide Between 60° and 100° from Measurement of the Boiling-point Elevation480

8．9 Molal Osmotic and Activity Coefficients of Electrolytes at Concentrations up to 0·1 M and at temperatures other than the freezing-point481

8．10Molal Osmotic Coefficients of Electrolytes at 25°:483

1∶1 Electrolytes,Tables 1-3483

2∶1 Electrolytes,Tables 4-6486

1∶2 Electrolytes,Table 6488

2∶2 and 3∶1 Electrolytes,Table 7489

Higher Valency Types,Table 8490

Mean Molal Activity Coefficients of Electrolytes at 25°:491

1∶1 Electrolytes,Tables 9-12491

2∶1 Electrolytes,Tables 13-14497

1∶2 Electrolytes,Table 15501

2∶2 and 3∶1 Electrolytes,Tables 16-17502

Higher Valency Types,Table 18503

Osmotic and Activity Coefficients at Higher Concentrations at 25°,Table 19504

Some recent Osnotic and Activity Coefficient Data at 25°,Table 20505

8．11Concentrations of Solutions giving Specified Water Activities at 25°;Water Activities of Saturated Solutions at 25°510

10．1 Values of the Function e？(Eq．10．20)at Round Values of f(z)511

10．2 Airy Integral Refinement of the＇Quarter-wave＇Approximation for the Interference Conditions512

11．1 Diffusion Coefficients of Dilute Aqueous Electrolyte Solutions513

11．2 Diffusion Coefficients of Concentrated Aqueous Electrolyte Solutions at 25°515

11．3 Individual Ionic Values of the Coefficient A2 in Viscosity Equation516

12．1Molality-scale Ionization Contants(as pKa Values)of Weak Electrolytes,and their Temperature-Variation:517

Tables 1-5(Aqueous Solations)517

Tables 6 and 7(Mixed Solvents)538

12．2 Ionization Constants of Water544

12．3 pH of Solutions545

14．1 Values of the Definite Integral Q(b)in Equation(14．2)549

14．2 Limiting Equivalent Conductivities and Dissociation Constants of some Salts in Organic Solvents at 25°550

14．3 Dissociation Constants of Ion-pairs on Fuoss＇Theory551