《Electrodeposition of Alloys PRINCIPLES and PRACTICE Volume 2》求取 ⇩

Part ⅢPRACTICAL CONSIDERATIONS AND SPECIFIC INFORMATION ON THE ELECTRODEPOSITION OF ALLOYS(CONTINUED)4

ALLOY GROUP B.MUTUAL ALLOYS OF CADMIUM,LEAD,TIN,AND ZINC4

22.Electrodeposition of Lead-Tin Alloys4

22.1Introduction4

22.2 Literature4

22.3 Electrodeposition of Lead-Tin Alloys from the Fluoborate Bath5

22.4 Electrodeposition of Lead-Tin Alloys from Baths Other Than the Fluoborate16

22.5 Curves of Current Density vs.Cathode Potential in the Electrodeposition of Lead-Tin Alloys19

22.6 Appearance and Structure of Electrodeposited Lead-Tin Alloys21

22.7 Properties of Electrodeposited Lead-Tin Alloys23

22.8 Protective Value of Coatings of Lead-Tin Alloys24

22.9 Reclamation of Lead and Tin as the Alloy24

22.10 Miscellaneous Applications of Electrodeposited Lead-Tin Alloys25

22.11 Electrodeposition of Ternary Alloys from a Modified Lead-Tin Fluoborate Bath26

References27

23.Electrodeposition of Tin-Zinc Alloys30

23.1Introduction30

23.2 Early Literature31

23.3 Types of Baths32

23.4 The Stannate-Cyanide Tin-Zinc Alloy Plating Bath32

23.5 Electrodeposition of Tin-Zinc Alloys from the Complexone Bath50

23.6 Pyrophosphate Bath52

23.7 Acid Baths52

23.8 Passivation of Tin-Zinc Coatings52

23.9 Structure and Appearance of Electrodeposited Tin-Zinc Alloys53

23.10 Properties of Electrodeposited Tin-Zinc Alloys53

23.11 Corrosion Resistance and Protective Value of Tin-Zinc Coatings53

23.12 Uses of the Alloy59

23.13 Stripping of Deposits59

23.14 Analysis of Deposits and Plating Baths and Measurement of Thickness of Deposits60

23.15 Specification60

23.16 Electrodeposition of Lead-Zinc Alloys61

References61

24.Electrodeposition of Cadmium-Tin Alloys65

24.1Introduction65

24.2 Literature65

24.3 Types of Baths66

24.4 Electrodeposition of Cadmium-Tin Alloys from Acid Baths67

24.5 Electrodeposition of Cadmium-Tin Alloys from the Stannate-Cyanide Bath73

24.6 Structure of Cadmium-Tin Alloys78

24.7 Static Potentials of Alloys79

24.8 Protective Value and Corrosion Resistance of Electro-deposited Cadmium-Tin Alloys80

24.9 Some Miscellaneous Properties of the Alloy83

24.10 Electrodeposition of Cadmium-Lead Alloys83

References83

25.Electrodeposition of Cadmium-Zinc and Related Ternary Alloys85

25.1Introduction85

25.2 Electrodeposition of Cadmium-Zinc Alloys from Cyanide Baths86

25.3 Electrodeposition of Cadmium-Zinc Alloys from Simple Salt Baths93

25.4 Appearance and Structure of Electrodeposited Cadmium-Zinc Alloys100

25.5 Properties and Protective Value of Cadmium-Zinc Alloys101

25.6 Electrodeposition of Ternary Alloys Containing Cadmidum,Zinc,and Tin or Mercury102

References107

ALLOY GROUP C.ELECTRODEPOSITION OF ALLOYS OF CHRO-MIUM,INDIUM,THALLIUM,MANGANESE,AND SOME OF THE OTHER LESS NOBLE METALS109

26.Electrodeposition of Chromium Alloys110

26.1Introduction110

26.2 Electrodeposition of Chromium Alloys from the Chromic Acid Bath111

26.3 Electrodeposition of Chromium Alloys from Baths Con-taining Trivalent Chromium Salts116

References134

27.Electrodeposition of Manganese Alloys137

27.1Introduction137

27.2 Literature138

27.3 Problems in the Electrodeposition of Manganese and Its Alloys139

27.4 Electrodeposition of Alloys of Manganese Containing Iron,Nickel,or Cobalt140

27.5 Electrodeposition of Manganese-Copper Alloys150

27.6 Electrodeposition of Manganese-Zinc Alloys152

27.7 Electrodeposition of Manganese-Tin Alloys153

27.8 Electrodeposition of Manganese-Selenium Alloys154

27.9 Electrodeposition of Other Manganese Alloys156

References156

28．Electrodeposition of Alloys of Indium,Thallium,and Gallium158

28.1General Survey158

28.2 Electrodeposition of Alloys of Indium158

28.3 Electrodeposition of Alloys of Thallium168

28.4 Electrodeposition of Gallium Alloys181

References181

29.Attempts to Electrodeposit Alloys of Some of the More Active Metals183

29.1General Discussion183

29.2 Factors That Aid the Codeposition of the More Active Metals184

29.3 Paucity of Examples of Individual Deposition or Codeposi-tion of Active Metals185

29.4 Attempts to Electrodeposit Alloys of Magnesium186

29.5 Attempts to Codeposit Aluminum187

29.6 Attempts to Deposit Alloys Containing Titanium or Zirco-nium188

29.7 Attempts to Codeposit Miscellaneous Other Active Metals189

References189

ALLOY GROUP D.ELECTRODEPOSITION OF SOME OF THE MORE IMPORTANT ALLOYS OF THE IRON-GROUP METALS,WITH SPECIAL REFERENCE TO ANOMALOUS CODEPOSITION191

30.Electrodeposition of Alloys Containing an Iron-Group Metal and Zinc or Cadmium194

30.1Zinc Alloys of the Iron-Group Metals194

30.2 Electrodeposition of Cadmium-Nickel Alloys228

References236

31.Electrodeposition of the Mutual Alloys of the Iron-Group Metals239

31.1General Survey239

31.2 Literature239

31.3 Survey of the Plating Processes for Depositing Mutual Alloys of the Iron-Group Metals242

31.4 Electrodeposition of Cobalt-Nickel Alloys from Simple Salt Baths246

31.5 Electrodeposition of Cobalt-Nickel Alloys from Baths of Complex Ions263

31.6 Notea on the Analysis of the Cobalt-Nickel Plating Bath and the Testing of the Deposits264

31.7 Electrodeposition of Iron-Nickel Alloys from Simple Salt Baths265

31.8 Electrodeposition of Iron-Nickel Alloys from Baths of Complex Ions278

31.9 Electrodeposition of Iron-Cobalt Alloys from Simple Salt Baths284

31.10 Electrodeposition of Cobalt-Iron-Nickel Alloys fromSimple Salt Baths288

31.11 Potentials Involved in the Codeposition of the Metals of the Iron-Group from Simple Salt Solutions291

31.12 The Anomalous Nature of the Mutual Codeposition of the Iron-Group Metals297

31.13 Structure of the Electrodeposited Mutual Alloys of the Iron-Group Metals299

31.14 Properties of Electrodeposited Iron-Group Metals303

31.15 Uses of the Electrodeposited Alloys of the Iron-Group Metals306

References308

32.Electrodeposition of Alloys of the Iron-Group Metals Containing Tin or Lead315

32.1Survey315

32.2 Electrodeposition of Nickel-Tin Alloys315

32.3 Electrodeposition of Nickel-Lead Alloys336

32.4 Electrodeposition of Cobalt-Tin Alloys339

References341

ALLOY GROUP E.INDUCED CODEPOSITION OF ALLOYS CON-TAINING TUNGSTEN,MOLYBDENUM,GERMANIUM,OR PHOS-PHORUS345

33.Electrodeposition of Tungsten Alloys Containing Cobalt,Nickel,and/or Iron347

33.1Introduction347

33.2 Literature347

33.3 Electrodeposition of Alloys from Acid Solutions351

33.4 Electrodeposition of Tungsten Alloys of the Iron-Group Metals from Alkaline Baths356

33.5 Relation between Cathode Potentials and Current Density in the Deposition of Tungsten Alloys386

33.6 Nonmetallic Inclusions in the Deposits388

33.7 Appearance of Electrodeposited Tungsten Alloys389

33.8 Structure of Electrodeposited Tungsten Alloys389

33.9 Properties of Electrodeposited Tungsten Alloys391

33.10 Potential Uses of Electrodeposited Tungsten Alloys397

33.11 Electrodeposition of Tungsten Alloys Containing Metals Other Than the Iron-Group Metals398

33.12 Attempts to Explain the Mechanism and the Characteristics of the Induced Codeposition of Tungsten399

References408

34.Electrodeposition of Alloys Containing Molyb-denum and Nickel,Cobalt,or Iron413

34.1Introduction413

34.2 Literature414

34.3 General Survey of Baths for Electrodepositing Molybdenum Alloys415

34.4 Acid Baths for Electrodepositing Molybdenum Alloys417

34.5 Electrodeposition of Molybdenum Alloys from Ammoniacal Baths429

34.6 Electrodeposition of Molybdenum Alloys from the Pyro-phosphate Bath443

34.7 Electrodeposition of Cobalt-Molybdenum Alloys from the Carbonate Bath448

34.8 Electrodeposition of Iron-Molybdenum Alloy from a Caustic Bath449

34.9 Electrodeposition of Cobalt-or Iron-Molybdenum Alloys from Miscellaneous Alkaline Baths Containing Organic Compounds449

34.10 Appearance,Structure,and Properties of Electrodeposited Alloys of Molybdenum and the Iron-Group Metals450

34.11 Electrodeposition of Other Molybdenum Alloys452

34.12 Mechanism of the Induced Codeposition of Molybdenum453

References454

35.Electrodeposition of Alloys Containing Phosphorus and Nickel or Cobalt457

35.1Introduction457

35.2 Composition of Plating Baths and Conditions of Plating458

35.3 Effect of Plating Variables on Composition of Electrodepo-sited Phosphorus Alloys461

35.4 Induced Codeposition and the cd-ptl Relations of the Phosphorus Alloys468

35.5 Properties of Electrodeposited Phosphorus Alloys470

35.6 Protective Value Afforded to Steel by Coatings of Phosphorus Alloys480

35.7 Applications of Electrodeposited Phosphorus Alloys481

35.8 Analyses of Baths and Deposits482

References482

36.Electrodeposition of Germanium Alloys484

36.1Introduction484

36.2 Electrodeposition of Copper-Germanium Alloy485

36.3 Electrodeposition of Alloys of Germanium Containing Nickel,Cobalt,or Silver488

36.4 Electrodeposition of Tin and Zinc Alloys of Germanium489

36.5 Gallium-Germanium Alloy490

References490

ALLOY GROUP F.ELECTRODEPOSITION OF ALLOYS OF SEVERAL METALS MORE NOBLE THAN HYDROGEN493

37.Electrodeposition of Gold Alloys494

37.1Background494

37.2 Literature495

37.3 Principles of Gold Plating from the Cyanide Bath498

37.4 The Electrodeposition of Decorative Gold Alloys of Various Colors500

37.5 Electrodeposition of Gold-Copper Alloys507

37.6 Electrodeposition of Gold-Silver Alloys524

37.7 Electrodeposition of Gold-Nickel and Gold-Cobalt Alloys532

37.8 Electrodeposition of Ternary and Quaternary Alloys Containing Gold and Copper,Silver,or Nickel533

37.9 Electrodeposition of Gold-Antimony Alloys534

37.10 Electrodeposition of Miscellaneous Alloys of Gold535

37.11 Thick Gold Alloy Deposits536

37.12 Electrodeposition of Gold Alloys from Acid Baths537

37.13 Analysis of Gold Alloy Plating Baths537

References538

38.Electrodeposition of Alloys of the Platinum Metals542

38.1General542

38.2 Alloys of the Platinum Metals with the Iron-Group Metals and Other Base Metals543

38.3 Mutual Alloys of the Platinum Metals544

38.4 Summary545

References545

39.Electrodeposition of Alloys Containing Antimony or Arsenic547

39.1Alloys of Antimony547

39.2 Electrodeposition of Alloys of Arsenic573

References575

40.Electrodeposition of Alloys of Bismuth577

40.1Introduction577

40.2 Electrodeposition of Bismuth-Copper Alloys578

40.3 Electrodeposition of Bismuth-Silver Alloys589

40.4 Electrodeposition of Bismuth-Lead Alloys596

References597

41.Electrodeposition of Alloys Containing Rhenium and the Iron-Group Metals598

41.1Background598

41.2 Electrodeposition of Alloys of Rhenium599

41.3 Properties of Electrodeposited Rhenium Alloys605

41.4 Miscellaneous605

References605

42.Electrodeposition of Alloys Containing Sulfur607

42.1Introduction607

42.2 Electrodeposition of Nickel-Sulfur Alloys607

42.3 Miscellaneous Sulfur Alloys613

References614

AUTHOR INDEX617

SUBJECT INDEX630

PATENT INDEX-VOLUMES Ⅰ AND Ⅱ651