《CHEMISTRY AND PHYSICS OF POLYCARBONATES》求取 ⇩

Ⅰ．Introduction1

Ⅱ．Historical3

Ⅲ．Chemistry of Polycarbonates9

1．Aliphatic Polycarbonates9

A．Preparation of Aliphatic Polycarbonates9

1．Preparation of Aliphatic Polycarbonates by Phosgenation9

2．Preparation of Aliphatic Polycarbonates by Reaction of Bis-Chlorocarbonic Acid Esters of Aliphatic Dihydroxy Compounds with Aliphatic Dihydroxy Compounds13

3．Preparation of Aliphatic Polycarbonates by Transesterfication of Aliphatic Dihydroxy Compounds with Carbonic Acid Diesters14

4．Preparation of Aliphatic Polycarbonates by Polycondensation of Bisalkyl or Bisaryl Carbonates of Aliphatic Dihydroxy Com-pounds18

5．Preparation of Aliphatic Polycarbonates by Polymerization of Cyclic Carbonates18

B．Properties of Aliphatic Polycarbonates20

2．Aliphatic-Aromatic Polycarbonates24

3．Aromatic Polycarbonates27

A．Preparation of Aromatic Polycarbonates31

1．Preparation of Aromatic Polycarbonates by Phosgenation of Aro-matic Dihydroxy Compounds in the Presence of Pyridine31

2．Preparation of Aromatic Polycarbonates by Interfacial Polycon-densation33

3．Isolation of Aromatic Polycarbonates from Their Respective Solutions41

4．Preparation of Aromatic Polycarbonates by Transesterification44

5．Other Methods of Preparation of Aromatic Polycarbonates51

6．Preparation of Polycarbonate Copolymers and Mixed Polycon-densates Containing Carbonate Groups53

A．Polycarbonate Copolymers53

B．Mixed Polyesters Containing Carbonic Acid Ester Groups as Well as Carboxylic Acid Ester Groups58

C．Mixed Polyesters Containing Carbonic Acid Ester Groups as Well as Urethane Groups60

D．Mixed Polyesters Containing Carbonic Acid Ester Groups as Well as Imine Carbonate or Siloxane Groups61

7．Crosslinking of Polycarbonates61

A．Influence of Radiation on Aromatic Polycarbonates and Poly-carbonate Copolymers62

B．Crosslinking of Aromatic Polycarbonates by Heating in the Presence of Air63

C．Crosslinking of Polycarbonates and Polycarbonate Copolymers Containing Tri- or Polyfunctional Groups64

D．Crosslinking of Polycarbonates by the Addition of Reactive Polyfunctional Compounds70

8．Compilation of the Most Important Polycarbonates and Polycar-bonate Copolymers Prepared to Date70

Ⅳ．The Production of the Most Important Raw Materials and Intermediates for Aromatic Polycarbonates77

1．Derivatives of 4,4＇-Dihydroxy-Diaryl Methane77

A．Production of Dihydroxy-Diaryl Methane Derivatives from Aromatic Hydroxy Compounds and Aldehydes or Ketones78

1．Reaction of Aromatic Hydroxy Compounds with Carbonyl Com-pounds in the Presence of Acidic Condensing Agents78

2．Reaction of Aromatic Hydroxy Compounds with Oxo Compounds in the Presence of Alkaline Condensing Agents83

B．Other Methods for the Preparation of 4,4＇-Dihydroxy-Diphenyl Meth-ane Derivatives84

C．Summary of the Most Important 4,4＇-Dihydroxy-Diphenyl Methane Derivatives Produced to Date85

2．Diphenyl Carbonate91

Ⅴ．Structure and Properties of Aromatic Polycarbonates99

1．Solubility of Aromatic Polyearbonates(1-5)99

2．Melting Range and Second-Order Transition Temperature of Aromatic Polycarbonates(1-4)101

3．Determination of the Molecular Data of Polycarbonates in Solution110

A．Fractionation of Bisphenol A Polycarbonate110

B．Diffusion and Sedimentation Measurements on Bisphenol A Polycar-bonate Solutions114

C．Light-Scattering Measurements on Bisphenol A Polycarbonate Solu-tions115

D．Determination of Molecular Weights and Second Osmotic Virial Coefficients of Bisphenol A Polycarbonates in Dilute Solution by Osmometric Methods117

E．Solution Viscosities of Bisphenol A Polycarbonates119

F．Molecular Dimensions of Bisphenol A Polycarbonate in Solution as Determined by Sedimentation,Diffusion,and Viscosity Measure-ments121

4．Melt Viscosity of Bisphenol A Polycarbonate124

5．Crystal Structure and Morphology of Bisphenol A Polycarbonate in the Nonstretched and Stretched States127

6．Mechanical and Thermal Properties and Properties under Dynamic Conditions of Bisphenol A Polycarbonate139

7．Electrical Properties of Aromatic Polycarbonates157

8．Refractive Index and Light Transmittance of Aromatic Polycarbonates165

9．Water Absorption,Water Vapor Permeability,and Gas Permeability of Aromatic Polycarbonates175

10．Aging and Chemical Resistance of Bisphenol A Polycarbonate180

11．Physiological Properties of Bisphenol A Polycarbonate184

12．Identification of Polycarbonates185

Ⅵ．The Manufacture and Use of Bisphenol A Polycarbonate Parts189

1．Film and Fibers190

2．Injection-Molded Parts,Extruded Tubes and Shapes,and Blow-Molded Articles194

A．Injection Molding194

B．Extrusion199

C．Compression Molding201

D．Machining202

E．Cold Forming202

F．Cementing,Welding,and Printing203

G．Foaming203

3．Aromatic Polycarbonate Paints and Coatings204

Author Index209

Subject Index217