《BRIDGED AROMATIC COMPOUNDS》

作者 编者
出版 ACADEMIC PRESS
参考页数 553
出版时间 1964（求助前请核对）  目录预览
ISBN号 无 — 求助条款
PDF编号 812478958（仅供预览，未存储实际文件）
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BRIDGED AROMATIC COMPOUNDS 1964 PDF电子版封面

NOMENCLATURE1

Polymethylene or Disubstituted Aromatic System2

Phenylene System3

Benzo system4

Ansa System5

Bicyclo System5

Cyclophane System6

A New System8

PREPARATION24

The Acyloin Cyclization Method27

The Friedel-Crafts Cyclization Method43

The Halo-Amine Cyclization Method66

The Halo-Ether Cyclization Method75

The wurtz Reaction88

The Ziegler Cyclization Method96

Cyclization by Pyrolysis of Acids and Their Salts100

Pyrolysis of Hydrocarbons105

The Hofmann Elimination Reaction Method106

Cyclization by Pyrolysis of Other Compounds112

The Ring-Contraction Method114

Cyclization by Oxidative Coupling115

Nonaromatic Routes to Bridged Aromatics121

The Depolymerization Cyclization Method131

The Dieckmann Cyclization Method133

Cyclization by Amide Formation136

Cyclization by Imine Formation142

Miscellaneous Methods of Preparing Cyclophanes147

Porphyrins and Related Compounds Containing Bridged Aromatic Nuclei176

Natural Products Containing Cyclophane Links178

References185

CHEMISTRY OF THE BRIDGED NUCLEUS201

Carbon-Hydrogen Substituents202

Halogen and Halogen-Containing Substituents208

Oxygen-Containing Substituents213

Nitrogen-Containing Substituents236

Sulfur-Containing Substituents244

Rearrangement of Cyclophane Bridges245

Hydrogenation of the Aromatic Nucleus247

Molecular Complexes of the Cyclophanes249

Inclusion Compounds of the Cyclophanes256

Photochemical Studies258

Dehydrogenation of Cyclophanes to Polycyclics259

Diels-Alder Reactions260

References262

CHEMISTRY OF THE BRIDGE267

Carbon-Hydrogen Substituents267

Oxygen-Containing Substituents282

Halogen Substituents316

Nitrogen and Sulfur Substituents320

Methylene Acidity324

Bridgehead Oxidations324

References326

DISSYMMETRY OF THE BRIDGED AROMATICS333

Text333

References357

ULTRAVIOLET ABSORPTION SPECTROSCOPY359

Text359

References382

INFRARED ABSORPTION SPECTROSCOPY385

Text385

References392

χ-RAY AND OTHER STRUCTURAL STUDIES393

Text393

References406

NUCLEAR AND ELECTRON MAGNETIC RESONANCE STUDIES407

Nuclear Magnetic Resonance407

Electron Paramagnetic Resonance419

References421

TABLES OF COMPOUNDS423

Tables424

References495

Author Index503

Subject Index525

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