《THE CHEMISTRY OF ISOBUTYRALDEHYDE AND ITS DERIVATIVES》

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参考页数 94
出版时间 1953（求助前请核对）  目录预览
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THE CHEMISTRY OF ISOBUTYRALDEHYDE AND ITS DERIVATIVES 1953 PDF电子版封面

INTRODUCTION1

SYNTHESIS3

Manufacture by the Oxo Process3

Manufacture from Isobutyl Alcohol3

Other Methods of Synthesis4

PHYSICAL PROPERTIES5

Isobutyraldehyde5

Isobutyl Alcohol6

Isobutyric Acid7

CHEMICAL PROPERTIES9

Acetal and Mercaptal Formation9

Acetylation10

Aldol Condensations10

Isobutyraldol and Derivatives10

Preparation10

Oxidation12

Reduction12

Mixed Aldols and Derivatives13

Hydroxypivalaldehyde and Derivatives17

Preparation17

Oxidation18

Reduction20

Reductive Amination20

Acetylation20

Condensations Other Than Aldol23

Acetoacetic Ester Reactions23

Acyloin Formation24

Azlactone Formation25

Cannizzaro Reaction25

Condensations with Miscellaneous Reagents26

Acetylene26

Chloroform26

Ethyl Dichloroacetate27

Ethylenimine27

Formamide27

2-Methylquinoline27

Nitroparaffins27

Schiff＇s Bases28

Secondary Amines28

Condensations with Unsaturated Compounds28

Ketene28

Olefins29

Unsaturated Ethers30

Cyanoethylation31

Ibanitrile Formation31

Ibanitrile Reactions31

Cyanohydrin Formation35

Knoevenagel Reaction35

Mannich Reaction36

Michael Addition38

Perkin Reaction39

Reformatsky Reaction40

Stobbe Reaction42

Telomerization42

Tischenko Reaction44

Dehydrogenation45

Friedel-Crafts Reaction45

Halogenation48

Nitrile Formation49

Organophosphorus Compound Formation51

Oxidation52

Pyrolysis55

Reduction56

Reductive Amination57

Sulfonation60

Trimerization61

APPLICATIONS63

Amino Acids63

Pantothenic Acid63

dl-Valine64

dl-Leucine64

a-Aminoisobutyrlc Acid65

Aminopivalic Acid66

Cellulose Esters66

Corrosion Inhibitors66

Gasoline Additives67

Hydraulic Fluids and Lubricants67

Insect-Controlling and Similar Agents67

Perfumes and Flavors68

Plasticizers70

Isobutyl Alcohol70

Dimethylmalonic Acid71

2,2,4-Trlmethyl-1,3-pentanediol71

2,2-Dimethyl-1,3-propanediol71

a,a-Dimethylglutaric Acid720

Isobutyric Acid720

Miscellaneous720

Polyamide and Polyester Intermediates79

Resins79

Solutizers80

Solvents80

Sulfonyldicarboxylic Acids80

Synthesis81

Polyesters81

Textile Assistants83

Vinyl Monomers83

HANDLING PRECAUTIONS85

Fire Hazards85

Storage and Transfer85

BIBLIOGRAPHY87

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