《THE KINETICS OF VINYL POLYMERIZATION BY RADICAL MECHANISMS》

作者	C.H.BAMFORD W.G.BARB A.D.JEN 编者
出版	LONDON BUTTERWORTHS SCIENTIFIC PUBLICATIONS
参考页数	318
出版时间	没有确切时间的资料目录预览
ISBN号	无 — 求助条款
PDF编号	811593198（仅供预览，未存储实际文件）
求助格式	扫描PDF（若分多册发行，每次仅能受理1册）

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1．GENERAL INTRODUCTION1

Historical development1

Component reactions of the overall polymerization3

Simplifying assumptions in calculations of the kinetics of vinyl polymerization7

Examples of the derivation of kinetic equations,using full simplifying assumptions12

Derivation of kinetic equations with omission of certain simplifing assumptions16

Special features of divinyl polymerization24

References27

2．THEORY OF THE DETERMINATION OF INDIVIDUAL RATE COEFFICIENTS AND OF RATES OF INITIATiON28

Individual rate coefficients28

Rates of initiation48

References53

3．KINETICS OF THE HOMOGENEOUS POLYMERIZATION OF VARIOUS VINYL MONOMERS55

Styrene55

Methyl methacrylate72

Miscellaneous acrylates and methacrylates81

Vinyl acetate84

Other monomers88

Effects of structure91

References93

4．HETEROGENEOUS POLYMERIZATION98

Introduction98

Vapour phase polymerization99

Bulk polymerization of liquid monomers with special reference to acrylonitrile103

The occlusion theory of heterogeneous polymerization111

Other bulk polymerizations117

Polymerization in the presence of preoipitants125

Popcorn polymerization128

Emulsion and suspension polymerization136

References143

5．COPOLYMERIZATION148

Introduction148

Theoretical treatment of copolymer composition149

Experimental studies of copolymer composition160

Theoretical significance of reactivity ratios165

Rates of copolymerization174

Transfer in oopolymerization181

Semi-vinyl copolymerization182

Graft and block copolymers197

References200

6．INITIATION,CHAIN TRANSFER,RETARDATION AND INHIBITION203

Introduction203

Initiation203

Chain transfer227

Inhibition and retardation243

References260

7．STATISTICAL ASPECTS OF VINYL POLYMERIZATION266

Calculation of molecular weight distributions in homopolymers269

Summary of distribution formulae295

Size and composition distributions incopolymers295

Limiting viscosity number as a funotion of molecular weight distribution298

Cross-linking and gelation301

References309

INDEX311

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