《CATALYSIS VOLUME 4》

作者	PAUL H·EMMETT 编者
出版	PEINHOLD PUBLISHING CORPLRATION
参考页数	570
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ISBN号	无 — 求助条款
PDF编号	811581258（仅供预览，未存储实际文件）
求助格式	扫描PDF（若分多册发行，每次仅能受理1册）

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1．THE THERMODYNAMICS OF THE HYDROGENATION OF CARBON MO-NOXIDE AND RELATED REACTIONS＆Robert B．Anderson1

Introduction1

Hydrogenation of Carbon Monoxide2

Hydrogenation of Carbon Dioxide9

Reaction of Water with Carbon Monoxide or Carbon9

Reactions of Hydrocarbons and Alcohols11

General Conclusions based on Thermodynamics of Synthesis14

Thermodynamics of Reactions of Iron,Cobalt,and Nickel19

2．CATALYSTS FOR THE FISCHER-TROPSCH SYNTHESIS＆Robert B．An-derson29

Scope of the Chapter29

The Development of Fischer-Tropsch Catalysts and Processes29

Experimental Methods for Testing Catalysts36

Cobalt and Nickel Catalysts46

Iron Catalysts119

Ruthenium Catalysts237

Sulfur-Poisoning of Fischer-Tropsch Catalysts242

3．KINETICS AND REACTION MECHANISM OF THE FISCHER-TROPSCH SYNTHESIS＆Robert B．Anderson257

Kinetics of the Fischer-Tropsch Synthesis257

Variations of the Fischer-Tropsch Synthesis298

Nature of the Catalytic Surface and Effect of Promoters323

Mechanism of the Fischer-Tropsch Synthesis335

4．CRYSTALLINE PHASES AND THEIR RELATION TO FISCHER-TROPSCH CATALYSTS＆L．J．E．Hofer373

Introduction373

The Nickel System of Catalysts382

The Cobalt System391

The Iron System406

5．THE ISOSYNTHESIS＆Ernst M．Cohn443

Purpose and History of the Synthesis443

Description of the Synthesis443

Preparation and Reactivation of Catalysts444

Apparatus for Activity Tests447

Synthesis Experiments449

Detailed Characterization of Products462

Determination of Motor Octane Number467

Mechanism of Synthesis and Function of Catalyst467

6．METHANATION＆Murray Greyson473

Introduction473

Chemistry and Thermodynamics of Methanation474

Catalysts481

Industrial Techniques506

Kinetics and Mechanisms of Reaction508

7．CATALYSIS IN THE LIQUID-PHASE HYDROGENATION OF COAL AND TAR＆S．N．W．Weller513

Introduction513

Wall Effects514

Influence of Vehicle and Catalyst Distribution515

Comparative Catalyst Tests519

Stability of Catalysts522

Catalysis and the Mechanism of Hydrogenation523

8．CATALYTIC CYCLIZATION AND AROMATIZATION OF HYDROCARBONS＆H．Steiner529

Introduction529

General Chemistry of the Reaction530

Thermodynamic Considerations535

Mechanism of the Reaction535

Cyclization Catalysts549

Technical Applications557

Author Index561

Subject Index567

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