《Table 1.Crystal Data and Details of Experiment for Complexes 1 and 2》
![《Table 1.Crystal Data and Details of Experiment for Complexes 1 and 2》](http://bookimg.mtoou.info/tubiao/gif/JGHX201901019_06500.gif)
本系列图表出处文件名:随高清版一同展现
《"Flexible Bis(benzimidazole)-based Ligands Directed the Structure Characteristics of Coordination Polymers Based on Diphenic Acid Co-ligands:Syntheses, Structures and Properties"》
aR=Σ|Fo|–|Fc|/|Fo|,w R=[Σw(Fo2–Fc2)2/Σw(Fo2)2]1/2
The well-shaped single crystals of complexes 1and 2 were selected for X-ray diffraction study.The unit cell parameters and intensity data were collected at 293 K on a Bruker SMART APEX II CCD diffractometer using a graphite-monochromated Mo Kα(λ=0.071073 nm)radiation.The structures were solved by direct methods using SHELXS program[20]package and refined by fullmatrix least-squares fitting on F2 by SHEXL-97[21].All non-hydrogen atoms were refined anisotropically.All hydrogen atoms of organic ligands were placed in geometrically idealized positions and constrained to ride on their parent atoms(Complex1:C–H=0.97?with Uiso (H)=1.2Ueq(C)for methylene groups,C–H=0.93?with Uiso(H)=1.4Ueq(C)for aromatic rings.Complex 2:C–H=0.97?with Uiso(H)=1.2Ueq(C)for methylene groups,C–H=0.93?with Uiso(H)=1.2Ueq(C)for aromatic rings) .The details of crystal parameters are summarized in Table 1,and the selected bond lengths are listed in Table 2.
图表编号 | XD0034856200 严禁用于非法目的 |
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绘制时间 | 2019.01.01 |
作者 | 屠长征、杨玉亭、许丽丽、晏帮领、汪帆 |
绘制单位 | College of Chemistry and Environmental Science,Qujing Normal University、College of Chemistry and Environmental Science,Qujing Normal University、College of Chemistry and Environmental Science,Qujing Normal University、College of Chemistry and Environmental |
更多格式 | 高清、无水印(增值服务) |