《Table 1 Crystal data and structure refinement for HL and complexes 1~5》

《Table 1 Crystal data and structure refinement for HL and complexes 1~5》   提示:宽带有限、当前游客访问压缩模式
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《五个吡嗪缩氨基硫脲过渡金属配合物的合成、结构和荧光性质(英文)》


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The X-ray diffraction measurement for HL and complexes 1~5 was performed on a Bruker SMART APEXⅡCCD diffractometer equipped with a graphite monochromatized Mo Kαradiation(λ=0.071 073 nm)by usingφ-ωscan mode.Semi-empirical absorption correction was applied to the intensity data using SADABS program[15].The structures were solved by direct methods and refined by full matrix least-square on F2using SHELXTL-97 program[16].All non-hydrogen atoms were refined anisotropically.All H atoms were positioned geometrically and refined using a riding model.Details of the crystal parameters,data collection and refinements are summarized in Table 1.