《Analytical Chemistry of Ruthenium》求取 ⇩

Chapter Ⅰ:PHYSICOCHEMICAL AND ANALYTICAL CHARACTERISTICS OF RUTHENIUM AND ITS COMPOUNDS1

Chapter Ⅱ:DETECTION OF RUTHENIUM12

Inorganic reagents for ruthenium12

Organic reagents for ruthenium16

Spot tests for ruthenium27

Chemical microscopic detection of ruthenium30

Detection of ruthenium by the catalytic action of its compounds35

Detection of ruthenium in a mixture of cations35

Chapter Ⅲ:CHEMICAL AND INSTRUMENTAL METHODS FOR THE DETERMINATION OF RUTHENIUM37

Gravimetric methods of determination of ruthenium37

Volumetric methods of determination of ruthenium52

Potentiometric titration methods57

Photometric determinations of ruthenium60

Fluorescence method of determination of ruthenium by 5-methyl-1,10-phenanthroline99

Electrochemical methods100

Polarographic methods117

Spectroscopic and X-ray methods127

Radiochemical methods132

Chapter Ⅳ:SEPARATION OF RUTHENIUM FROM THE ACCOMPANYING ELEMENTS144

Methods involving isolation of ruthenium tetroxide144

Separation of osmium and ruthenium tetroxides163

Separation of ruthenium from platinum metals166

Separation of ruthenium from alkaline earth metals and magnesium168

Chromatographic separation of ruthenium from other elements169

Chapter Ⅴ:DETERMINATION OF RUTHENIUM IN NATURAL MATERIALS AND INDUSTRIAL PRODUCTS174

The separation of platinum metals from the accompanying elements175

Assay methods for the separation of platinum metals176

Chemical methods of separation of platinum metals181

Determination of ruthenium in concentrates190

Determination of ruthenium in slurries and slags192

Determination of ruthenium in osmiridium194

Determination of ruthenium in the wastes of refining industry196

Analysis of silver bead197

Analysis of alloys containing ruthenium198

Determination of impurities in refined ruthenium202

Analytical procedures for the determination of ruthenium in various materials203

APPENDIX214

Determination of ruthenium in fluorides214

Methods of preparation of various ruthenium compounds216

Ruthenium compounds used as indicators220

BIBLIOGRAPHY223

SUBJECT INDEX247

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